The crystal structure bis{hexakis(1-methyl-1H-imidazole-κ1N)cobalt(II)} tetrakis(μ3-oxido)-octakis(μ2-oxido)-tetradecaoxido-octamolybdate(VI), C24H36CoMo4N12O13
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چکیده
منابع مشابه
Crystal structure of 2-ethyl-4-methyl-1-(2-oxido-3,4-dioxocyclobut-1-en-1-yl)-1H-imidazol-3-ium
In the title inner salt molecule, C10H10N2O3, the four-membered cyclobutene ring is twisted by 7.1 (2)° with respect to the five-membered imidazole ring. The crystal packing exhibits an R 2 (2)(9) hydrogen-bonding ring motif through N-H⋯O and C-H⋯O inter-actions. The potential non-linear optical properties were studied by a computational ab initio calculations performed at the DFT/B3LYP/6-31++G...
متن کاملPoly[[2-(3-pyridinio)-1H,3H +-benzimidazolium] [μ4-oxido-di-μ3-oxido-tetra-μ2-oxido-hexaoxidotetramolybdenum(VI)]]
The reaction of MoO(3) with 2-(3-pyrid-yl)benzoimidazole and water in the presence of MnSO(4)·5H(2)O at 453 K under hydro-thermal conditions afforded the title compound, {(C(12)H(11)N(2))[Mo(4)O(13)]}(n), in which infinite molybdenum oxide anionic chains are charge-balanced by diprotonated 2-(3-pyrid-yl)benzoimidazole (H(2)3-PBIM(2+)) cations. Eight [MoO(6)] octa-hedra are edge-shared, forming ...
متن کاملPoly[octakis(1H-imidazole-κN 3)octa-μ-oxido-tetraoxidodicopper(II)tetravanadate(V)]
In the title inorganic-organic hybrid compound, [Cu(2)V(4)O(12)(C(3)H(4)N(2))(8)](n), the V(V) ion is tetra-coordinated by four O atoms and the Cu(II) ion is hexa-coordinated by four N atoms from four imidazole ligands and two O atoms from two tetra-hedral vanadate (VO(4)) units in a distorted octa-hedral geometry. The structure consists of two-dimensional sheets constructed from centrosymmetri...
متن کاملCrystal structure of 4,5-dinitro-1H-imidazole
The title compound, C3H2N4O4, forms crystals with two mol-ecules in the asymmetric unit which are conformationally similar. With the exception of the O atoms of the nitro groups, the mol-ecules are essentially planar. In the crystal, adjacent mol-ecules are associated by N-H⋯N hydrogen bonds involving the imidazole N-H donors and N-atom acceptors of the unsaturated nitro-gen of neighboring ring...
متن کاملHexa-μ2-chlorido-μ4-oxido-tetrakis[(3-methyl-5-phenyl-1H-pyrazole-κN 2)copper(II)]
The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl-pyrazole ligand, three Cl(-) anions, and one O(2-) anion. The geometry at each Cu(II) atom is distorted ...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 2020
ISSN: 2197-4578,1433-7266
DOI: 10.1515/ncrs-2020-0289